Transition metal acyl complexes describes organometallic complexes containing one or more acyl (RCO) ligands. Such compounds occur as transient intermediates in many industrially useful reactions, especially carbonylations . [ 2 ]

Transition metal acyl complexes describes organometallic complexes containing one or more acyl (RCO) ligands. Such compounds occur as transient intermediates in many industrially useful reactions, especially carbonylations .

May 1, 1991 · Deoxygenative Reduction of Diruthenium Carbonyl Complexes (η5-C5H4R)2Ru2(μ-CO)2(CO)2 with Hydrosilanes Leading to Bridging Methylene Complexes (η5-C5H4R)2Ru2(μ-CH2)n(μ-CO)2-n(CO)2 (n = 1, 2; R = H, CH3).

Jun 6, 2022 · The formation of benzoyl(benzoato)palladium complexes via a stoichiometric reaction between benzoyl fluorides, Pd(OAc)2, a hydrosilane and a phosphine is reported. NMR studies of the acyl palladium...

In this Account, we outline the potential of alkylated Mn (I)-carbonyl complexes for the activation of nonpolar and moderately polar E–H (E = H, B, C, Si) bonds and disclose our successful approach for the utilization of complexes in the field of homogeneous catalysis.

Sep 20, 1995 · In this account we summarize our work in this area concentrating specifically on the following topics: (i) the Mo-agostic acyl structure; (ii) the chemical reactivity of coordinated -q2-acyl ligand and (iii) the conversion of an "q2-acyl into an "q2-imin- oacyl function by reaction with an isocyanide. 2.

Aug 25, 2004 · Acyl Complexes Derived from Pentacarbonyl Iron. Phosphine-Substituted Chiral-at-Iron Derivatives and Analogs. Diiron Enoyl Acyl Complexes. Iron-Substituted Enones and Enals. References

Acyl- and alkyl-iridium intermediates have been isolated, including some containing only one phosphine ligand. The best studied decarbonylation reagent is chlorotris(triphenylphos phine)rhodium(I), RhCI(PPh3h, which decarbonylates aldehydes and acyl and aroyl halides under mild conditions (i.e., thermally in solution at temperatures below lOO°C).

Aug 13, 2024 · Persistent radicals facilitate numerous selective radical coupling reactions. Here, we have identified acyl triazole as a new and versatile moiety for generating persistent radical intermediates...

In this Account, we outline the potential of alkylated Mn (I)-carbonyl complexes for the activation of nonpolar and moderately polar E–H (E = H, B, C, Si) bonds and disclose our successful approach for the utilization of complexes in the field of homogeneous catalysis.