
Mechanism for hydrolysis of enol ether to aldehyde
From what I can tell, you are having more trouble with the acidic hydrolysis of an enol ether to an aldehyde. As has been pointed out by some comments, your proposed mechanism is not …
organic chemistry - Mechanism of enolether formation with ethyl ...
Apr 13, 2015 · Some argue that the reaction actually proceeds through the ketal (rather than the hemiketal) since ketals can be isolated in these reactions. Others argue that just because the …
organic chemistry - How to form an acetal from an enol ether ...
Jun 7, 2017 · I am having trouble understanding how the protecting group (ethylene glycol) is applied to the alkene next to the ether of highlighted step above. I thought maybe TsOH …
Mechanism of a cyclization reaction - why does an enol ether form?
Mar 10, 2017 · That intermediate explains the need for aqueous $\ce{H+}$. Similarly to how the intermediate shown in the question wouldn't be my first guess (or, apparently, yours), I'm …
Mechanism of enol ether formation - Chemistry Stack Exchange
Jun 1, 2015 · Mechanism of enol ether formation. Ask Question Asked 9 years, 9 months ago. Modified 9 years, 9 months ago.
Role of NaI in Formation of Silyl Enol Ethers using Chloro …
Apr 26, 2019 · I am forming silyl enol ethers using Chloro(trimethyl)silane (TMSCl), and below is an experimental protocol I am following. Silyl Enol Ether Synthesis. In an oven-dried 100 mL …
Selectivity in Thermodynamically-Driven Silyl Enol Ether Formation, …
Mar 4, 2021 · Mechanism of enol ether formation. 1. Relative basicity of fluorine and oxygen in silyl ether deprotection. 7.
organic chemistry - Mechanism of deprotection of enol thioether ...
Oct 10, 2023 · Removal of the thioenol ether protecting group gives the aldehyde function, and under the acidic conditions the β-hydroxy group eliminates to give the mainly (E)-unsaturated …
The use of silyl enol ethers over aza-enolates
Feb 25, 2019 · Thus, whether the nucleophile is very strong and basic, in the case of an aza-enolate, or relatively weaker, in the case of a silyl enol ether, the alkylation would still proceed …
organic chemistry - Mechanism for reaction of enol ether with HBr ...
Apr 25, 2018 · Mechanism for reaction of enol ether with HBr. Ask Question Asked 6 years, 9 months ago.