
(PDF) Nature of the bias-dependent symmetry reduction of iron ...
Aug 15, 2015 · We found that the FePc bulk system displays a magnetic state resulting from the metallic central Fe atom. However, the adsorbed FePc partially loses its magnetization when it is deposited on...
The adsorption of iron phthalocyanine on graphite: A scanning ...
Sep 1, 2007 · Different adsorption phases of iron phthalocyanine (FePc) on highly oriented pyrolitic graphite (HOPG) have been characterized by scanning tunnelling microscopy (STM). Evaporation of FePc onto the graphite (0 0 0 1) surface, kept at room temperature, results in the formation of three-dimensional molecular islands.
Iron phthalocyanine (FePc) is less prone to symmetry breaking than its CoPc and CuPc counterparts [6,12,18,19]; a clear symmetry breaking has only been reported for FePc/Cu(111) [12], while...
f‐p‐d Gradient Orbital Coupling Induced Spin State Enhancement …
Feb 21, 2025 · Here, an effective f-p-d (Eu–O–Fe) gradient orbital coupling strategy is introduced by integrating FePc with Eu 2 O 3 (FePc/Eu 2 O 3) to enhance the spin state and ORR performance of the Fe center through a precisely designed, scalable synthetic approach.
Control of Molecular Orbital Ordering Using a van der Waals …
Dec 16, 2022 · We first study the FE order of ultrathin SnTe monolayer grown by molecular beam epitaxy (MBE) on highly oriented pyrolytic graphite (HOPG) substrate (see Experimental Section and Figure S1, Supporting Information).
HREEL spectroscopy of FePc on HOPG at submonolayer coverage.
To support this hypothesis, we measured the HREELS of submonolayer FePc film on top of highly oriented pyrolitic graphite (HOPG) (see Fig. 6). It is clear that FePc adopts flat-lying geometry on...
Proximity Effect of Epitaxial Iron Phthalocyanine Molecules on …
Sep 1, 2021 · Here, we investigate the magnetic proximity effect of epitaxial iron phthalocyanine (FePc) molecules on high-quality monolayer and bilayer graphene devices on hexagonal boron nitride substrates by probing the local and nonlocal transport.
Nanoscale Oxygenous Heterogeneity in FePC Glass for Highly …
Sep 21, 2023 · The results revealed that the FeP/FePCO exhibited the highest ΔE ads value of −5.53 eV; in comparison, the ΔE ads values of FePC, Fe 3 P/FePC, and FeOOH were −3.14, −4.07, and −4.72 eV, respectively. Surprisingly, FeOOH exhibited higher adsorption energy than FePC and Fe 3 P/FePC.
Supramolecular tuning of supported metal phthalocyanine …
Mar 13, 2023 · We find that the presence of oxygen functional groups on the carbon nanotube (CNT) surface generates electron-deficient cobalt phthalocyanine (CoPc) and that this optimally modulates the...
Iron phthalocyanine with coordination induced electronic localization ...
Aug 20, 2020 · Iron phthalocyanine (FePc) is a promising non-precious catalyst for the oxygen reduction reaction (ORR). Unfortunately, FePc with plane-symmetric FeN 4 site usually exhibits an unsatisfactory...
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