Transition-metal allyl complex - Wikipedia
Transition-metal allyl complexes are coordination complexes with allyl and its derivatives as ligands. Allyl is the radical with the connectivity CH 2 CHCH 2, although as a ligand it is …
Synthesis and isolation of highly reactive .eta.3-allyl alkyne ...
A Platinum Complex-Catalyzed Reaction of 3-Chloro-1,3-diene Monoepoxides with Carbon Nucleophiles Involving Nucleophilic Substitution at the Central Carbon Atom of the π-Allyl …
.eta.3-Allyl complexes of molybdenum: the preparation and …
Electron-Deficient Vanadium(III) Alkyl and Allyl Complexes with Amidinate Ancillary Ligands. Organometallics 1998 , 17 (18) , 4090-4095. https://doi.org/10.1021/om980431e
New [Mo(eta3-allyl)(CO)2L3]+ complexes with monodentate or
Mar 7, 2005 · Cationic complexes [Mo (eta (3)-allyl) (CO)2L3]+ (L3 = either nitrogen-donor tridentate ligand or three monodentate ligands) were prepared in high yield and under mild …
An Unusual, Selective .eta.3-.eta.1 Allyl Isomerization in a Chiral ...
May 1, 1994 · Cyclopropanes by Nucleophilic Attack of Mono-and Diaryl-Substituted (?3-Allyl)palladium Complexes: Aryl Effect and Stereochemistry. Angewandte Chemie …
eta(3)-Allyl carbonyl complexes of group 6 metals: Structural …
This review is focused on pi-allylic representatives of low-cost Group-6 metals bearing one or more carbonyl ligand, the coordination sphere being complemented with eta(5) …
(eta(3)-Allyl)palladium Complexes Bearing …
Dec 3, 2001 · (eta(3)-Allyl)palladium Complexes Bearing Diphosphinidenecyclobutene Ligands: Highly Active Catalysts for the Hydroamination of 1,3-Dienes This work was supported by a …
Utilisation of an eta(3)-allyl hydride complex, formed by UV ...
Oct 21, 2008 · Utilisation of an eta(3)-allyl hydride complex, formed by UV irradiation, as a controlled source of 16-electron (eta(5)-C(5)Me(5))Rh(CH(2)[double bond, length as m …
Transformation of .eta.3-allyl to .mu.-.eta.1,.eta.3-allylidene in ...
Generation of Dimethylsilylene and Allylidene Holmium Complexes from Trimethylsilylated Allyl Ligands. Journal of the American Chemical Society 2006, 128 (30) , 9622-9623. …
Toward Alkane Functionalization Effected with Cp*W(NO)(alkyl)(eta(3 ...
Cp*W (NO) (n-alkyl) (eta (3)-allyl) complexes result from the selective activations of the terminal C-H bonds of alkanes.